Shi Heping, De Saptarshi, Wang Qiaoling, Gao Shuanhu, Wang Xiao, Chen Chuo
Department of Biochemistry, UT Southwestern Medical Center, 5323 Harry Hines Boulevard, Dallas, TX 75390-9038, United States.
Tetrahedron Lett. 2015 Jun 3;56(23):3225-3227. doi: 10.1016/j.tetlet.2014.12.054.
We report herein the synthesis of a fully functionalized B,C,D-ring system of lancifodilactone F. The key transformations involve an arene-olefin -photocycloaddition reaction and a palladium-catalyzed oxidative C-C cleavage reaction to establish its B,C-rings.
我们在此报告兰西多内酯F的全官能化B、C、D环系统的合成。关键转化包括芳烃-烯烃光环化加成反应和钯催化的氧化C-C裂解反应以构建其B、C环。
