Piriou P, Soulet C, Acero J L, Bruchet A, Von Gunten U, Suffet I H
Suez-Environnement, CIRSEE. 38, rue du Président Wilson, 78230 Le Pecq, France.
Water Sci Technol. 2007;55(5):85-94. doi: 10.2166/wst.2007.166.
The formation of bromophenols during chlorination of phenol- and bromide-containing waters can be critical for taste and odour problems in drinking waters. The work performed has confirmed that flavour threshold concentrations of some bromophenols are in the ng/L range. In addition, under typical drinking water conditions, kinetic experiments and model simulations performed have shown that (1) bromination is the predominant reaction pathway, (2) bromophenol reaction kinetics are rapid leading to taste-and-odour episodes that last for short periods of 10-20 min, (3) increasing phenol concentration and pH tends to increase taste and odour intensity, (4) increasing chlorine or bromide concentrations tends to shorten the duration of the taste-and-odour episode.
含酚和溴化物的水在氯化过程中形成溴酚可能是饮用水中味道和气味问题的关键所在。已开展的研究证实,某些溴酚的风味阈值浓度处于纳克/升范围内。此外,在典型的饮用水条件下,所进行的动力学实验和模型模拟表明:(1)溴化是主要反应途径;(2)溴酚反应动力学很快,会导致持续10 - 20分钟短时间的味道和气味事件;(3)增加苯酚浓度和pH值往往会增加味道和气味强度;(4)增加氯或溴化物浓度往往会缩短味道和气味事件的持续时间。