一种温和的铜（I）催化共轭二烯的区域选择性双胺化反应。
A mild Cu(I)-catalyzed regioselective diamination of conjugated dienes.
作者信息
Yuan Weicheng, Du Haifeng, Zhao Baoguo, Shi Yian
机构信息
Department of Chemistry, Colorado State University, Fort Collins, Colorado 80523, USA.
出版信息
Org Lett. 2007 Jun 21;9(13):2589-91. doi: 10.1021/ol071105a. Epub 2007 May 31.
PMID:17536815
Abstract
This paper describes a novel diamination process that uses CuCl as catalyst and di-tert-butyldiaziridinone as nitrogen source. A wide variety of conjugated dienes and a triene can be effectively diaminated in good yields with generally high regioselectivity under mild reaction conditions.
摘要
本文描述了一种新型的双胺化过程，该过程使用氯化铜作为催化剂，二叔丁基二氮杂环丁烷作为氮源。在温和的反应条件下，多种共轭二烯和一种三烯能够以良好的产率和通常较高的区域选择性被有效地双胺化。
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