金（I）催化的甲硅烷基烯酮酰胺和氨基甲酸酯与炔烃的区域选择性环化反应。
Gold(I)-catalyzed regioselective cyclizations of silyl ketene amides and carbamates with alkynes.
作者信息
Minnihan Ellen C, Colletti Steven L, Toste F Dean, Shen Hong C
机构信息
Department of Medicinal Chemistry, Merck Research Laboratories, Merck & Co. Inc., P.O. Box 2000, Rahway, NJ 07065, USA.
出版信息
J Org Chem. 2007 Aug 3;72(16):6287-9. doi: 10.1021/jo071014r. Epub 2007 Jul 11.
PMID:17625890
Abstract
The gold(I)-catalyzed regioselective cyclizations of silyl ketene amides or carbamates with alkynes were utilized to construct cyclopentanes or dehydro-delta-lactams.
摘要
金（I）催化的甲硅烷基烯酮酰胺或氨基甲酸酯与炔烃的区域选择性环化反应被用于构建环戊烷或脱氢-δ-内酰胺。
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