通过非酶促去对称化对洛贝林进行对映选择性合成。
Enantioselective synthesis of lobeline via nonenzymatic desymmetrization.
作者信息
Birman Vladimir B, Jiang Hui, Li Ximin
机构信息
Department of Chemistry, Washington University, Campus Box 1134, One Brookings Drive, St. Louis, Missouri 63130, USA.
出版信息
Org Lett. 2007 Aug 16;9(17):3237-40. doi: 10.1021/ol071064i. Epub 2007 Jul 20.
PMID:17658751
Abstract
Lobeline has been prepared in enantiopure form via desymmetrization of lobelanidine with use of BTM, a nonenzymatic enantioselective acyl transfer catalyst.
摘要
通过使用BTM（一种非酶对映选择性酰基转移催化剂）对洛贝兰定进行去对称化反应，已制备出对映体纯形式的洛贝林。
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