Eymery Joël, Rieutord François, Favre-Nicolin Vincent, Robach Odile, Niquet Yann-Michel, Fröberg Linus, Mårtensson Thomas, Samuelson Lars
CEA Grenoble, Département de Recherche Fondamentale sur la Matière Condensée, Service des Matériaux et Microstructures, 17 rue des Martyrs, 38054 Grenoble Cedex 9, France.
Nano Lett. 2007 Sep;7(9):2596-601. doi: 10.1021/nl070888q. Epub 2007 Aug 28.
Quantitative structural information about epitaxial arrays of nanowires are reported for a InAs/InP longitudinal heterostructure grown by chemical beam epitaxy on an InAs (111)B substrate. Grazing incidence X-ray diffraction allows the separation of the nanowire contribution from the substrate overgrowth and gives averaged information about crystallographic phases, epitaxial relationships (with orientation distribution), and strain. In-plane strain inhomogeneities, intrinsic to the nanowires geometry, are measured and compared to atomistic simulations. Small-angle X-ray scattering evidences the hexagonal symmetry of the nanowire cross-section and provides a rough estimate of size fluctuations.
报道了通过化学束外延在InAs(111)B衬底上生长的InAs/InP纵向异质结构的纳米线外延阵列的定量结构信息。掠入射X射线衍射能够将纳米线的贡献与衬底上的过度生长区分开来,并给出有关晶体相、外延关系(包括取向分布)和应变的平均信息。测量了纳米线几何结构固有的面内应变不均匀性,并与原子模拟进行了比较。小角X射线散射证明了纳米线横截面的六边形对称性,并提供了尺寸波动的粗略估计。