Nuclear magnetic resonance at high pressure.

Nuclear magnetic resonance relaxation measurements at high pressure provide unique information about the microscopic behavior of liquids. This article presents the principles of this technique; illustrates its usefulness by several specific examples of studies of molecular liquids, water, and supercritical dense fluids; and indicates the promising future of high-resolution nuclear magnetic resonance spectroscopy at high pressure with examples of studies of chemical exchange and homogeneous catalytic processes.