芳炔插入碳-卤西格玛键：芳环的区域选择性酰化反应
Insertion of arynes into carbon-halogen sigma-bonds: regioselective acylation of aromatic rings.
作者信息
Yoshida Hiroto, Mimura Yasuhiro, Ohshita Joji, Kunai Atsutaka
机构信息
Department of Applied Chemistry, Graduate School of Engineering, Hiroshima University, Higashi-Hiroshima 739-8527, Japan.
出版信息
Chem Commun (Camb). 2007 Jun 21(23):2405-7. doi: 10.1039/b701581j.
DOI:10.1039/b701581j
PMID:17844761
Abstract
Arynes were found to insert into carbon-halogen sigma-bonds of various acid halides, enabling acyl and halogen moieties to be introduced simultaneously into adjacent positions of aromatic rings.
摘要
人们发现芳炔可插入各种酰卤的碳-卤西格玛键中，从而能够将酰基和卤素部分同时引入芳环的相邻位置。
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