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Olefinic ester and diene ring-closing metathesis using a reduced titanium alkylidene.

作者信息

Iyer Karthik, Rainier Jon D

机构信息

Department of Chemistry, University of Utah, Salt Lake City, UT 84112, USA.

出版信息

J Am Chem Soc. 2007 Oct 24;129(42):12604-5. doi: 10.1021/ja073880r. Epub 2007 Sep 27.

Abstract
摘要

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Synthesis of an A-E gambieric acid subunit with use of a C-glycoside centered strategy.
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Ruthenium-catalyzed olefin metathesis double-bond isomerization sequence.
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Synthesis of oxygen- and nitrogen-containing heterocycles by ring-closing metathesis.
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A unified approach to differentially linked beta-C-disaccharides by ring-closing metathesis.
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C-glycosides to fused polycyclic ethers. A formal synthesis of (+/-)-hemibrevetoxin B.
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Synthesis of Polycyclic Ethers by Two-Directional Double Ring-Closing Metathesis.
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