Schumacher Gary E, Antonucci Joseph M, O'Donnell Justin N R, Skrtic Drago
Paffenbarger Research Center, American Dental Association Foundation, 100 Bureau Drive, Gaithersburg, MD 20899, USA.
J Am Dent Assoc. 2007 Nov;138(11):1476-84. doi: 10.14219/jada.archive.2007.0084.
Amorphous calcium phosphate (ACP) composites release calcium and phosphate ions in aqueous environments, which may lead to deposition of apatitic mineral in tooth structure. The authors evaluate the strength of the composite/adhesive/dentin bond shear bond strength (SBS) for ACP basing-composites after various periods of water aging.
The authors made the experimental composites by using two resin matrices with various ACPs or a commercial strontium ion-leachable glass. They applied successive coats of a dentin adhesive and basing composite to an acid-etched dentin surface and photopolymerized them. They added a commercial resin-based composite and light cured it. They determined the specimens' SBS after they were aged in water for various periods at 37 degrees C.
The SBS of the ACP composites was 18.3 +/- 3.5 megapascals, independent of filler type, resin composition and water-aging interval. After 24 hours of water aging, 92.6 percent of surfaces showed the adhesive failure. After two weeks of water aging, adhesive/cohesive failures were predominant in unmilled and milled ACP composites.
The SBS of ACP composites appears to be unaffected by filler type or immersion time for up to six months. The type of adhesive failure occurring with prolonged aqueous exposure is affected by filler type.
These materials may be effective remineralizing/antidemineralizing agents and may be clinically applicable as adhesives, protective liners and bases, orthodontic cements and pit-and-fissure sealants.
无定形磷酸钙(ACP)复合材料在水环境中会释放钙和磷酸根离子,这可能导致牙体结构中磷灰石矿物质的沉积。作者评估了不同水老化时间后,基于ACP的复合材料的复合树脂/黏结剂/牙本质黏结抗剪强度(SBS)。
作者使用两种含有不同ACP的树脂基质或一种市售的可释放锶离子的玻璃制成实验性复合材料。他们在酸蚀后的牙本质表面依次涂抹一层牙本质黏结剂和垫底复合材料,并进行光固化。然后添加一种市售的树脂基复合材料并进行光固化。在37℃的水中对样本进行不同时间的老化处理后,测定其SBS。
ACP复合材料的SBS为18.3±3.5兆帕,与填料类型、树脂成分和水老化时间间隔无关。水老化24小时后,92.6%的表面出现黏结剂破坏。水老化两周后,未研磨和研磨后的ACP复合材料中,黏结剂/内聚破坏占主导。
ACP复合材料的SBS在长达六个月的时间内似乎不受填料类型或浸泡时间的影响。长时间水暴露后发生的黏结剂破坏类型受填料类型的影响。
这些材料可能是有效的再矿化/抗脱矿剂,在临床上可用作黏结剂、保护性衬层和垫底材料、正畸黏固剂以及窝沟封闭剂。