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[法兰克福(奥得河)地区水域商业池塘和鱼苗场鱼类中有机氯农药、多氯联苯和氯酚的残留量]

[Residues of organochlorine pesticides, PCB's and chlorophenols in fish from commercial ponds and fish hatcheries from the waters in the area of Frankfurt (Oder)].

作者信息

Hollstein A

机构信息

Hygieneinstitut Frankfurt (Oder), Bundesrepublik Deutschland.

出版信息

Nahrung. 1991;35(10):1029-39. doi: 10.1002/food.19910351006.

DOI:10.1002/food.19910351006
PMID:1800905
Abstract

Fishes from fish-hatcheries, lakes and the river Oder in the area of the former district Frankfurt (Oder) were analysed for organochlorine pesticides (HCB, aldrin, HCH-isomeres, DDD, DDE, DDT, endrin, toxaphen and dieldrin), polychlorinated biphenyles and penta- and tetrachlorophenole. A clean up-procedure using acidic digestion mixture has been compared with a column-extraction-procedure followed by column chromatography on aluminia. Furthermore the simultaneous determination of the organochlorine pesticides, PCB's and chlorophenoles by acidic silicagel-extraction is described. The identification and quantification was realized by packed-column and capillary-gaschromatography including electron-capture-detection. The investigations show, that the permissible levels were only reached up to 2 to 10% with exception of toxaphen and pentachlorophenole. Average 50% of the toxaphen- and pentachlorophenole-values were found near the tolerance levels settled for these substances. The application of both substances in the area of the former German Democratic Republic until today can be regarded as a reason for this. The results of our investigations are comparable to last publications on fish contamination in the area of the previous Federal Republic of Germany.

摘要

对来自养鱼场、湖泊以及前法兰克福(奥得河)地区的奥得河中的鱼类进行了分析,检测其有机氯农药(六氯苯、艾氏剂、六氯环己烷异构体、滴滴滴、滴滴伊、滴滴涕、异狄氏剂、毒杀芬和狄氏剂)、多氯联苯以及五氯苯酚和四氯苯酚的含量。已将使用酸性消解混合物的净化程序与柱萃取程序以及随后在氧化铝上进行柱色谱法的程序进行了比较。此外,还描述了通过酸性硅胶萃取同时测定有机氯农药、多氯联苯和氯苯酚的方法。通过填充柱和毛细管气相色谱法(包括电子捕获检测)实现了鉴定和定量。调查表明,除毒杀芬和五氯苯酚外,仅2%至10%的鱼类达到了允许水平。发现毒杀芬和五氯苯酚含量平均值的50%接近为这些物质设定的耐受水平。直至今日,在原德意志民主共和国地区使用这两种物质可被视为造成这种情况的一个原因。我们的调查结果与以前德意志联邦共和国地区有关鱼类污染的最新出版物结果具有可比性。

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