控制与仅含铁氢化酶亚位点相关的双铁单元处的一氧化碳结合。
Controlling carbon monoxide binding at di-iron units related to the iron-only hydrogenase sub-site.
作者信息
Xu Fenfen, Tard Cédric, Wang Xiufeng, Ibrahim Saad K, Hughes David L, Zhong Wei, Zeng Xirui, Luo Qiuyan, Liu Xiaoming, Pickett Christopher J
机构信息
Department of Chemistry, Nanchang University, Nanchang, 330031, China.
出版信息
Chem Commun (Camb). 2008 Feb 7(5):606-8. doi: 10.1039/b712805c. Epub 2007 Nov 16.
DOI:10.1039/b712805c
PMID:18209804
Abstract
Carbon monoxide binding by displacement of a pendant hemi-labile ligand at a di-iron site can be substantially 'switched-on' via a ligand protonation pathway which is competitive with metal-metal bond protonation.
摘要
通过与金属-金属键质子化相竞争的配体质子化途径，在双铁位点上通过取代一个悬垂的半不稳定配体来实现一氧化碳结合，这一过程可以被显著“开启”。
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