• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

Direct, iridium-catalyzed enantioselective and regioselective allylic etherification with aliphatic alcohols.

作者信息

Ueno Satoshi, Hartwig John F

机构信息

Department of Chemistry, University of Illinois Urbana-Champaign, Urbana, IL 61801, USA.

出版信息

Angew Chem Int Ed Engl. 2008;47(10):1928-31. doi: 10.1002/anie.200705267.

DOI:10.1002/anie.200705267
PMID:18236502
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2819336/
Abstract
摘要
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3351/2819336/208a264c1a76/nihms173106f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3351/2819336/208a264c1a76/nihms173106f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3351/2819336/208a264c1a76/nihms173106f1.jpg

相似文献

1
Direct, iridium-catalyzed enantioselective and regioselective allylic etherification with aliphatic alcohols.铱直接催化脂肪醇的对映选择性和区域选择性烯丙基醚化反应。
Angew Chem Int Ed Engl. 2008;47(10):1928-31. doi: 10.1002/anie.200705267.
2
Cross-metathesis/iridium(I)-catalyzed allylic etherification strategy: (iterative) catalytic asymmetric synthesis of syn- and anti-1,2-diols.交叉复分解/铱（I）催化的烯丙基醚化策略：（迭代）催化不对称合成顺式和反式1,2 - 二醇
Angew Chem Int Ed Engl. 2013 Apr 8;52(15):4203-6. doi: 10.1002/anie.201209112. Epub 2013 Jan 15.
3
Regio- and enantioselective iridium-catalyzed intermolecular allylic etherification of achiral allylic carbonates with phenoxides.铱催化的非手性烯丙基碳酸酯与酚盐的区域和对映选择性分子间烯丙基醚化反应
J Am Chem Soc. 2003 Mar 26;125(12):3426-7. doi: 10.1021/ja029790y.
4
Enantio-, diastereo-, and regioselective iridium-catalyzed asymmetric allylic alkylation of acyclic β-ketoesters.非环β-酮酯的对映选择性、非对映选择性和区域选择性铱催化不对称烯丙基烷基化反应。
J Am Chem Soc. 2013 Nov 20;135(46):17298-301. doi: 10.1021/ja4097829. Epub 2013 Nov 6.
5
Iridium-catalyzed intermolecular allylic etherification with aliphatic alkoxides: asymmetric synthesis of dihydropyrans and dihydrofurans.铱催化脂肪醇盐的分子间烯丙基醚化反应：二氢吡喃和二氢呋喃的不对称合成
Angew Chem Int Ed Engl. 2004 Sep 13;43(36):4794-7. doi: 10.1002/anie.200460214.
6
Iridium-Catalyzed Enantioselective Allylic Substitution of Aliphatic Esters with Silyl Ketene Acetals as the Ester Enolates.铱催化的手性烯丙基取代反应，用硅基烯酮缩醛作为酯烯醇盐。
Angew Chem Int Ed Engl. 2017 Jul 17;56(30):8887-8891. doi: 10.1002/anie.201704354. Epub 2017 Jun 27.
7
Regio- and stereoselective synthesis of alkyl allylic ethers via gold(I)-catalyzed intermolecular hydroalkoxylation of allenes with alcohols.通过金（I）催化的丙二烯与醇的分子间氢烷氧基化反应实现区域和立体选择性合成烷基烯丙基醚。
Org Lett. 2008 May 15;10(10):2079-81. doi: 10.1021/ol800646h. Epub 2008 Apr 16.
8
A novel palladium-catalyzed hydroalkoxylation of alkenes with a migration of double bond.一种新型的钯催化烯烃氢烷氧基化反应，伴有双键迁移。
Org Biomol Chem. 2008 Apr 21;6(8):1344-8. doi: 10.1039/b800838h. Epub 2008 Mar 17.
9
Steric parameters in the Ir-catalyzed regio- and diastereoselective isomerization of primary allylic alcohols.铱催化的伯烯丙醇的区域和立体选择性异构化中的立体参数。
Org Lett. 2013 Dec 20;15(24):6170-3. doi: 10.1021/ol403023x. Epub 2013 Nov 12.
10
Identification of an activated catalyst in the iridium-catalyzed allylic amination and etherification. Increased rates, scope, and selectivity.铱催化烯丙基胺化和醚化反应中活性催化剂的鉴定。反应速率、范围和选择性的提高。
J Am Chem Soc. 2003 Nov 26;125(47):14272-3. doi: 10.1021/ja038319h.

引用本文的文献

1
Synthesis of vinyl-substituted alcohols using acetylene as a C2 building block.以乙炔作为C2结构单元合成乙烯基取代的醇类。
Chem Sci. 2022 Dec 23;14(7):1912-1918. doi: 10.1039/d2sc06400f. eCollection 2023 Feb 15.
2
Stereoselective Construction of Tertiary Homoallyl Alcohols and Ethers by Nucleophilic Substitution at Quaternary Carbon Stereocenters.通过在季碳立体中心的亲核取代反应立体选择性构建三级偕丙基醇和醚。
Angew Chem Int Ed Engl. 2023 Jan 16;62(3):e202212425. doi: 10.1002/anie.202212425. Epub 2022 Dec 13.
3
Enantioselective and Diastereodivergent Allylation of Propargylic C-H Bonds.对映选择性和非对映异构发散性炔丙基 C-H 键的烯丙基化反应。
J Am Chem Soc. 2022 Aug 31;144(34):15480-15487. doi: 10.1021/jacs.2c07297. Epub 2022 Aug 17.
4
Enantio- and regioselective asymmetric allylic substitution using a chiral aminophosphinite ruthenium complex: an experimental and theoretical investigation.使用手性氨基亚磷酸酯钌配合物的对映选择性和区域选择性不对称烯丙基取代：实验与理论研究
RSC Adv. 2021 Dec 9;11(62):39319-39327. doi: 10.1039/d1ra06824e. eCollection 2021 Dec 6.
5
Metal Triflate-Promoted Allylic Substitution Reactions of Cinnamyl Alcohol in the Presence of Orthoesters and Acetals.原甲酸酯和缩醛存在下金属三氟甲磺酸盐促进的肉桂醇烯丙基取代反应
ACS Omega. 2019 Sep 23;4(14):15985-15991. doi: 10.1021/acsomega.9b02059. eCollection 2019 Oct 1.
6
Chirality Transfer in Gold(I)-Catalysed Direct Allylic Etherifications of Unactivated Alcohols: Experimental and Computational Study.金（I）催化未活化醇的直接烯丙基醚化反应中的手性转移：实验与计算研究
Chemistry. 2015 Sep 21;21(39):13748-57. doi: 10.1002/chem.201501607. Epub 2015 Aug 6.
7
Diastereo- and Enantioselective Iridium Catalyzed Coupling of Vinyl Aziridines with Alcohols: Site-Selective Modification of Unprotected Diols and Synthesis of Substituted Piperidines.铱催化的氮杂环丙烷与醇的非对映和对映选择性偶联：未保护二醇的位点选择性修饰及取代哌啶的合成
J Am Chem Soc. 2015 Jun 24;137(24):7915-20. doi: 10.1021/jacs.5b04404. Epub 2015 Jun 15.
8
Gold(I)-catalysed direct thioetherifications using allylic alcohols: an experimental and computational study.使用烯丙醇的金（I）催化直接硫醚化反应：一项实验与计算研究
Chemistry. 2014 Sep 1;20(36):11540-8. doi: 10.1002/chem.201403293. Epub 2014 Jul 30.
9
Enantioselective synthesis of hindered cyclic dialkyl ethers catalytic oxa-Michael/Michael desymmetrization.受阻环状二烷基醚的对映选择性合成：催化氧杂-迈克尔/迈克尔去对称化反应
Chem Sci. 2013 Jul 1;4(7):2828-2832. doi: 10.1039/C3SC51022K.
10
The regio- and stereospecific intermolecular dehydrative alkoxylation of allylic alcohols catalyzed by a gold(I) N-heterocyclic carbene complex.金（I）N-杂环卡宾配合物催化的烯丙醇的区域和立体选择性分子间脱水烷氧基化反应。
Chemistry. 2013 Mar 4;19(10):3437-44. doi: 10.1002/chem.201203987. Epub 2013 Jan 24.

本文引用的文献

1
Regioselective and enantioselective iridium-catalyzed allylation of enamines.铱催化的烯胺区域选择性和对映选择性烯丙基化反应
J Am Chem Soc. 2007 Jun 27;129(25):7720-1. doi: 10.1021/ja071455s. Epub 2007 Jun 2.
2
Iridium-catalyzed, asymmetric amination of allylic alcohols activated by Lewis acids.铱催化的、由路易斯酸活化的烯丙醇的不对称胺化反应。
J Am Chem Soc. 2007 Jun 20;129(24):7508-9. doi: 10.1021/ja0730718. Epub 2007 May 25.
3
Copper-catalyzed cross-coupling reaction of grignard reagents with primary-alkyl halides: remarkable effect of 1-phenylpropyne.格氏试剂与伯烷基卤化物的铜催化交叉偶联反应：1-苯基丙炔的显著影响
Angew Chem Int Ed Engl. 2007;46(12):2086-9. doi: 10.1002/anie.200603451.
4
Development of new P-chiral phosphorodiamidite ligands having a pyrrolo[1,2-c]diazaphosphol-1-one unit and their application to regio- and enantioselective iridium-catalyzed allylic etherification.具有吡咯并[1,2-c]二氮杂磷杂环戊-1-酮单元的新型P-手性亚磷酰胺酯配体的开发及其在区域和对映选择性铱催化的烯丙基醚化反应中的应用。
J Org Chem. 2007 Feb 2;72(3):707-14. doi: 10.1021/jo0615403.
5
Iridium(I)-catalyzed regio- and enantioselective decarboxylative allylic amidation of substituted allyl benzyl imidodicarbonates.铱（I）催化取代烯丙基苄基亚胺二碳酸酯的区域和对映选择性脱羧烯丙基酰胺化反应
J Am Chem Soc. 2007 Jan 31;129(4):774-5. doi: 10.1021/ja067966g.
6
Asymmetric synthesis of alpha-substituted aldehydes by Pd-catalyzed asymmetric allylic alkylation-alkene isomerization-Claisen rearrangement.钯催化的不对称烯丙基烷基化-烯烃异构化-克莱森重排反应合成α-取代醛的不对称合成法
Org Lett. 2006 Dec 21;8(26):6007-10. doi: 10.1021/ol0624878.
7
Catalytic enantioselective decarboxylative protonation.催化对映选择性脱羧质子化反应
J Am Chem Soc. 2006 Sep 6;128(35):11348-9. doi: 10.1021/ja063335a.
8
Iridium-catalyzed enantioselective synthesis of allylic alcohols: silanolates as hydroxide equivalents.铱催化的烯丙醇对映选择性合成：硅醇盐作为氢氧化物等价物
Angew Chem Int Ed Engl. 2006 Sep 18;45(37):6204-7. doi: 10.1002/anie.200602408.
9
Enantioselective palladium-catalyzed decarboxylative allylic alkylations.对映选择性钯催化的脱羧烯丙基烷基化反应。
Angew Chem Int Ed Engl. 2006 Aug 11;45(32):5246-8. doi: 10.1002/anie.200601889.
10
Salt-free iridium-catalyzed asymmetric allylic aminations with N,N-diacylamines and ortho-nosylamide as ammonia equivalents.以N,N-二酰基胺和邻位 nosylamide 作为氨等效物的无盐铱催化不对称烯丙基胺化反应
Angew Chem Int Ed Engl. 2006 Aug 18;45(33):5546-9. doi: 10.1002/anie.200601472.