Braibanti Marco, Vigolo Daniele, Piazza Roberto
Dipartimento di Chimica, Materiali e Ingegneria Chimica Politecnico di Milano, 20133 Milano, Italy.
Phys Rev Lett. 2008 Mar 14;100(10):108303. doi: 10.1103/PhysRevLett.100.108303. Epub 2008 Mar 12.
Thermophoresis is particle drift induced by a temperature gradient. By measuring the full temperature dependence of this effect for polystyrene latex suspensions, we show that the thermophoretic mobility (or "thermal diffusion coefficient") D(T) is basically independent on particle size, in particular, when the interfacial properties of the colloidal particles are carefully standardized by adsorbing a surfactant layer on the particle surface. Even more, all investigated systems show values of D(T) which are very close to those measured for simple micellar solutions of the adsorbed surfactant. Our findings could be of relevance for downsizing microfluidics to the nanometric range.
热泳是由温度梯度引起的粒子漂移。通过测量聚苯乙烯胶乳悬浮液中这种效应的完整温度依赖性,我们表明热泳迁移率(或“热扩散系数”)D(T)基本上与粒径无关,特别是当通过在粒子表面吸附一层表面活性剂来仔细规范胶体粒子的界面性质时。甚至,所有研究的系统所显示的D(T)值都与吸附的表面活性剂的简单胶束溶液所测得的值非常接近。我们的发现可能与将微流体缩小到纳米范围有关。