钯催化的新型N-芳基肽衍生物有氧氧化裂解和环化反应
New palladium-catalyzed aerobic oxidative cleavage and cyclization of N-aryl peptide derivatives.
作者信息
El Kaïm Laurent, Gamez-Montaño Rocio, Grimaud Laurence, Ibarra-Rivera Tannya
机构信息
Ecole Nationale Supérieure des Techniques Avancées, 75015 Paris, France.
出版信息
Chem Commun (Camb). 2008 Mar 21(11):1350-2. doi: 10.1039/b716849g. Epub 2008 Jan 18.
DOI:10.1039/b716849g
PMID:18389130
Abstract
Oxidative cleavage and cyclization cascades of N-aryl peptides have been achieved under palladium catalysis with air as the sole stoichiometric oxidant.
摘要
在钯催化下，以空气作为唯一的化学计量氧化剂，实现了N-芳基肽的氧化裂解和环化串联反应。
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