Gherardi M, Gatto M P, Gordiani A, Paci E, Proietto A
Istituto Superiore per la Prevenzione E la Sicurezza del Lavoro, Dipartimento Igiene del Lavoro, Via Fontana Candida 1, 00040 Monte Porzio Catone, RM.
G Ital Med Lav Ergon. 2007 Jul-Sep;29(3 Suppl):553-5.
Hygienists are interested in hexavalent chromium due to its genotoxic and carcinogenic effect on humans. The use of products containing hexavalent chromium is decreasing in many industrial fields because of the substitution with less-toxic compounds. In the aeronautical industry, however, the chromate are added to primer paint as a corrosion inhibitor of aircrafts surfaces: so hexavalent chromium compounds are available in many primers with a composition ranging from 10% to 13%. The application of these primers by using electrostatic guns potentially exposes painting and coating workers at high concentrations of aerosols containing Cr(VI). The aim of the present study is the evaluation of professional exposure to hexavalent chromium during aircraft painting, by adopting both environmental personal sampling and biological monitoring. To valuate workers exposure levels the personal measurements results have been compared with the exposure limit values (TLV-TWA) and the urinary chromium contents with the biological exposure indices (IBE). Moreover the strategy of coupling environmental sampling with biological monitoring seems to be a useful instrument to measure the validity of the individual protection devices.
由于六价铬对人体具有遗传毒性和致癌作用,卫生学家对其颇感兴趣。由于用毒性较小的化合物进行替代,许多工业领域中含六价铬产品的使用正在减少。然而,在航空工业中,铬酸盐作为飞机表面的腐蚀抑制剂被添加到底漆中:因此,许多底漆中都含有六价铬化合物,其含量范围为10%至13%。使用静电喷枪涂抹这些底漆可能会使喷漆和涂层工人暴露于高浓度含六价铬的气溶胶中。本研究的目的是通过采用环境个人采样和生物监测来评估飞机喷漆过程中职业性接触六价铬的情况。为了评估工人的接触水平,已将个人测量结果与接触限值(时间加权平均阈限值)进行了比较,并将尿铬含量与生物接触指数进行了比较。此外,将环境采样与生物监测相结合的策略似乎是衡量个体防护设备有效性的一种有用手段。