一种意外的钌配合物及其在仲醇动态动力学拆分中作为催化剂的独特行为。
An unexpected ruthenium complex and its unique behavior as catalyst in dynamic kinetic resolution of secondary alcohols.
作者信息
Chen Qihui, Yuan Chengye
机构信息
State Key Laboratory of Bio-organic and Natural Products Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 354 Feng-lin Road, Shanghai, China.
出版信息
Chem Commun (Camb). 2008 Nov 14(42):5333-5. doi: 10.1039/b811627j. Epub 2008 Sep 17.
DOI:10.1039/b811627j
PMID:18985201
Abstract
A ruthenium complex was accidentally synthesized and its unique catalytic behavior in dynamic kinetic resolution of various types of secondary alcohols, particularly for those bearing additional functional groups, is described.
摘要
一种钌配合物被意外合成，并描述了其在各种仲醇的动态动力学拆分中独特的催化行为，特别是对于那些带有额外官能团的仲醇。
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