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废弃滴滴涕生产工厂及其周边土壤和水中的滴滴涕残留

DDT residue in soil and water in and around abandoned DDT manufacturing factory.

作者信息

Jan M Rasul, Shah Jasmin, Khawaja Mahmood A, Gul Kashif

机构信息

Institute of Chemical Sciences, N.W.F.P., University of Peshawar, Peshawar, Pakistan.

出版信息

Environ Monit Assess. 2009 Aug;155(1-4):31-8. doi: 10.1007/s10661-008-0415-2. Epub 2008 Jun 28.

Abstract

Dichlorodiphenyltrichloroethane (DDT) belongs to one of the most hazardous groups of chemicals called persistent organic pollutants. Many organochlorine pesticides including p,p(')-DDT are long lasting due to their non-degradability can travel to distant places and being fat soluble can accumulate in animals and human bodies. Due to the persistent nature of p,p(')-DDT, its adverse environmental and health impacts, the present study was undertaken to examine the residual p,p(')-DDT in and around abandoned p,p(')-DDT manufacturing factory in Amman Gharh, Nowshera, NWFP. Samples of soil, sediments and water were collected in and around the factory area, nearby p,p(')-DDT stores, main factory drain leading to river Kabul and nearby villages. Standard procedures were used for the collection, transportation and storage of samples for analyses. Extraction of each sample for p,p(')-DDT analyses was carried out in triplicates using Soxhelt extraction. p,p(')-DDT contents in the samples were analyzed by capillary GC with electron capture detector. Most of the samples collected up to half kilometer distance from the site of the DDT factory were found contaminated. Further the level of p,p(')-DDT decreased with increasing depth from top to bottom and with distance from the site. The results indicate that there is no immediate threat to underground water reservoirs.

摘要

滴滴涕(DDT)属于一类危害性极大的化学物质,即持久性有机污染物。包括p,p′-滴滴涕在内的许多有机氯农药由于难以降解,因而持久存在,它们能够传播到遥远的地方,并且因其脂溶性而会在动物和人体中蓄积。鉴于p,p′-滴滴涕的持久性、其对环境和健康的不利影响,本研究旨在检测位于西北边境省瑙谢拉县安曼加尔废弃的p,p′-滴滴涕制造工厂及其周边地区的p,p′-滴滴涕残留情况。在工厂区域内及其周边、附近的p,p′-滴滴涕储存点、通往喀布尔河的工厂主排水管道以及附近村庄采集了土壤、沉积物和水样。采用标准程序进行样品的采集、运输和储存以便分析。使用索氏提取法对每个样品进行p,p′-滴滴涕分析提取,共进行三次重复操作。采用带有电子捕获检测器的毛细管气相色谱法分析样品中的p,p′-滴滴涕含量。在距离滴滴涕工厂厂址半公里范围内采集的大多数样品都被发现受到了污染。此外,p,p′-滴滴涕的含量从地表到地下随深度增加以及随与厂址距离的增加而降低。结果表明,地下水库目前没有受到直接威胁。

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