Ghorai Prasanta, Dussault Patrick H
Department of Chemistry, University of Nebraska-Lincoln, Lincoln, Nebraska 68588-0304, USA.
Org Lett. 2008 Oct 16;10(20):4577-9. doi: 10.1021/ol801859c. Epub 2008 Sep 11.
Re2O7 in CH3CN is a remarkably efficient and mild catalyst for the peroxyacetalization of ketones, aldehydes, or acetals by H2O2 to generate 1,1-dihydroperoxides. Me3SiOReO3 and methyl rhenium trioxide (MTO) are also effective catalysts under these reaction conditions.
在乙腈中的Re2O7是一种用于酮、醛或缩醛通过H2O2进行过氧缩醛化反应以生成1,1 - 二氢过氧化物的极其高效且温和的催化剂。在这些反应条件下，三甲基硅基三氧化铼（Me3SiOReO3）和三氧化甲基铼（MTO）也是有效的催化剂。
