六水合氯化锶温和高效地催化酮和醛与水相 H2O2 反应生成相应的偕二氢过氧化物。
Mild and efficient strontium chloride hexahydrate-catalyzed conversion of ketones and aldehydes into corresponding gem-dihydroperoxides by aqueous H2O2.
机构信息
Faculty of Chemistry, Bu-Ali Sina University, 65178 Hamadan, Iran.
出版信息
Molecules. 2010 Mar 8;15(3):1433-41. doi: 10.3390/molecules15031433.
Abstract
SrCl2 x 6 H2O has been shown to act as an efficient catalyst for the conversion of aldehydes or ketones into the corresponding gem-dihydroperoxides (DHPs) by treatment with aqueous H2O2 (30%) in acetonitrile. The reactions proceed under mild and neutral conditions at room temperature to afford good to excellent yields of product.
摘要
六水氯化锶（SrCl2 x 6 H2O）已被证明是一种有效的催化剂，可通过在乙腈中用 30%的过氧化氢水溶液处理将醛或酮转化为相应的偕二氢过氧化物（DHPs）。反应在温和的中性条件下于室温下进行，可获得良好至优异的产物收率。
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