锰催化的芳基格氏试剂与卤代烯烃之间的交叉偶联反应。
Manganese-catalyzed cross-coupling reaction between aryl Grignard reagents and alkenyl halides.
作者信息
Cahiez Gérard, Gager Olivier, Lecomte Fabien
机构信息
Department of Chemistry, CNRS-Université de Paris 13, Bobigny, France.
出版信息
Org Lett. 2008 Nov 20;10(22):5255-6. doi: 10.1021/ol802273e. Epub 2008 Oct 16.
PMID:18922008
Abstract
Aryl Grignard reagents react stereospecifically with alkenyl halides in the presence of manganese chloride (10%) to afford good yields of cross-coupling products.
摘要
在氯化锰（10%）存在下，芳基格氏试剂与卤代烯烃发生立体专一性反应，能以良好的产率得到交叉偶联产物。
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