钯催化的有机金（I）试剂与有机亲电试剂的交叉偶联反应。
Palladium-catalyzed cross-coupling reactions of organogold(I) reagents with organic electrophiles.
机构信息
Departamento de Química Fundamental, Universidade da Coruña, Facultade de Ciencias, A Zapateira, s/n, Spain.
出版信息
Chemistry. 2010 Aug 23;16(32):9905-9. doi: 10.1002/chem.201000726.
PMID:20564296
Abstract
The palladium-catalyzed cross-coupling reaction of organogold(I) reagents (alkyl, alkenyl, aryl, and alkynyl) with organic electrophiles, such as aryl and alkenyl halides, aryl triflates, benzyl bromide, and benzoyl chloride is reported. The reaction takes place, under palladium catalysis, at room temperature with short reaction times to give the corresponding cross-coupling products in high yields.
摘要
报道了钯催化的有机金（I）试剂（烷基、烯基、芳基和炔基）与有机亲电试剂（如芳基和烯基卤化物、芳基三氟甲磺酸酯、溴化苄和苯甲酰氯）的交叉偶联反应。在钯催化下，该反应在室温下进行，反应时间短，以高产率得到相应的交叉偶联产物。
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