Anastos Nicole, Barnett Neil W, Lewis Simon W, Gathergood Nicholas, Scammells Peter J, Sims D Noel
School of Biological and Chemical Sciences, Deakin University, Geelong, Vic. 3217, Australia.
Talanta. 2005 Aug 15;67(2):354-9. doi: 10.1016/j.talanta.2004.11.038.
A simple, rapid and sensitive method for the determination of psilocin and psilocybin is described. This is the first report on the determination of psilocin and psilocybin using flow injection analysis with acidic potassium permanganate and tris(2,2'-bipyridyl)ruthenium(II) chemiluminescence. The limits of detection (signal-to-noise ratio=3) are 9x10(-10)M and 3x10(-10)M for psilocin and psilocybin, respectively. A concise synthetic route for psilocin in three steps from readily available starting materials is also described. The structures were elucidated on the basis of spectroscopic data.
本文描述了一种简单、快速且灵敏的测定裸盖菇素和脱磷酸裸盖菇素的方法。这是首次关于使用酸性高锰酸钾和三（2,2'-联吡啶）钌（II）化学发光流动注射分析测定裸盖菇素和脱磷酸裸盖菇素的报告。裸盖菇素和脱磷酸裸盖菇素的检测限（信噪比 = 3）分别为9×10⁻¹⁰ M和3×10⁻¹⁰ M。还描述了一种以容易获得的起始原料通过三步合成裸盖菇素的简洁合成路线。根据光谱数据阐明了结构。
