Ring expansions and contractions of metalloporphyrins.
作者信息
Callot Henry J
机构信息
Institut de Chimie, Université Louis Pasteur, 1 rue Blaise Pascal, 67000, Strasbourg, France.
出版信息
Dalton Trans. 2008 Dec 7(45):6346-57. doi: 10.1039/b807066k. Epub 2008 Oct 9.
DOI:10.1039/b807066k
PMID:19002318
Abstract
Ring expansions or contractions of metalloporphyrins are unusual reactions. In this review, the author will show how the step by step analysis of two serendipitous reactions allows one to unveil their mechanism and to point out the key role of nickel ion in these rearrangements.
摘要
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