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大气中农药的污染:液相、气相和颗粒相的测定。

Atmospheric contamination by pesticides: Determination in the liquid, gaseous and particulate phases.

机构信息

Laboratoire de Physico-Chimie de l'Atmosphère, Centre de Géochimie de la Surface (CNRS), Université Louis Pasteur, rue Goethe 28, F-67083, Strasbourg Cedex.

出版信息

Environ Sci Pollut Res Int. 1997;4(3):172-80. doi: 10.1007/BF02986327.

DOI:10.1007/BF02986327
PMID:19002404
Abstract

Between 1991 and 1993, 18 fogwater samples, 31 rainwater samples and 17 atmosphere (gas and particles) samples were analysed for 13 pesticides (pp'DDT,pp'DDD,pp'DDE, aldrin, dieldrin, lindane, hexachlorobenzene, fenpropathrin, mecoprop, methyl-parathion, atrazine, isoproturon and aldicarb). The samples were collected in a rural area where some of the compounds are in use (experimental INRA farm, "Institut National de la Recherche Agronomique" in Colmar, Eastern France, 80,000 inhabitants). This paper briefly presents the analytical methodology used and, in detail, the contamination level of the different atmospheric phases. The contamination levels are roughly constant throughout the year in all the atmospheric phases and the most abundant pesticides are those commonly used on the experimental INRA farm and other surrounding farms. Nevertheless, some pesticides not used since the 1970s such as 1,1-Bis(4-chlorophenyl)-2,2,2-trichloroethane (pp'DDT) and 2,2-Bis(4-chlorophenyl)-1,1-dichloroethane (pp 'DDD) are also detected in the atmosphere of Colmar. A small increase in the pesticide concentrations in the atmosphere (gas and particles) was observed during treatments.

摘要

1991 年至 1993 年间,在法国东部阿尔萨斯地区的一个农村地区(科马尔的法国国家农业研究院(INRA)的实验农场,有 8 万居民),采集了 18 个雾水样本、31 个雨水样本和 17 个大气(气体和颗粒)样本,分析了 13 种农药(pp'DDT、pp'DDD、pp'DDE、艾氏剂、狄氏剂、林丹、六氯苯、百菌清、甲草胺、甲基对硫磷、莠去津、异丙隆和涕灭威)。本文简要介绍了所使用的分析方法,并详细介绍了不同大气相的污染水平。在所有大气相全年的污染水平大致保持不变,最丰富的农药是那些在实验 INRA 农场和其他周围农场常用的农药。然而,一些自 20 世纪 70 年代以来未使用的农药,如 1,1-双(4-氯苯基)-2,2,2-三氯乙烷(pp'DDT)和 2,2-双(4-氯苯基)-1,1-二氯乙烷(pp 'DDD)也在科马尔的大气中被检测到。在处理过程中,大气(气体和颗粒)中的农药浓度略有增加。

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本文引用的文献

1
Chemical composition of fogwater in an urban area: Strasbourg (France).城市地区雾水的化学成分:法国斯特拉斯堡
Environ Pollut. 1996;94(3):345-54. doi: 10.1016/s0269-7491(96)00064-4.
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A multiresidue method for determination of trace levels of pesticides in air and water.一种用于测定空气和水中痕量农药的多残留方法。
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Evaporation of DDT.滴滴涕的蒸发
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Pesticides in fog.雾中的农药。
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A multiresidue method by high performance liquid chromatography-based fractionation and gas chromatographic determination of trace levels of pesticides in air and water.一种基于高效液相色谱分离和气相色谱法测定空气和水中痕量农药的多残留方法。
Arch Environ Contam Toxicol. 1990 Jul-Aug;19(4):583-92. doi: 10.1007/BF01059079.
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A multiclass, multiresidue analytical method for determining pesticide residues in air.一种用于测定空气中农药残留的多类别、多残留分析方法。
Arch Environ Contam Toxicol. 1975;3(1):55-71. doi: 10.1007/BF02221131.
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A multiclass, multiresidue analytical method for pesticides in water.一种用于水中农药的多类别、多残留分析方法。
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8
Evaluation of polyurethane foam for sampling of pesticides, polychlorinated biphenyls and polychlorinated naphthalenes in ambient air.聚氨酯泡沫用于采集环境空气中农药、多氯联苯和多氯萘的评估。
Anal Chem. 1977 Oct;49(12):1668-72. doi: 10.1021/ac50020a014.