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纳米颗粒负载且可磁回收的钯（Pd）催化剂：一种具有高周转数的选择性可持续氧化方案。

Nanoparticle-supported and magnetically recoverable palladium (Pd) catalyst: a selective and sustainable oxidation protocol with high turnover number.

作者信息

Polshettiwar Vivek, Varma Rajender S

机构信息

Sustainable Technology Division, National Risk Management Research Laboratory, U. S. Environmental Protection Agency, MS 443, Cincinnati, Ohio 45268, USA.

出版信息

Org Biomol Chem. 2009 Jan 7;7(1):37-40. doi: 10.1039/b817669h. Epub 2008 Nov 13.

DOI:10.1039/b817669h
PMID:19081941
Abstract

A magnetic nanoparticle-supported Pd catalyst was readily prepared from inexpensive starting materials and shown to catalyze various oxidation reactions with high turnover number (TON) and excellent selectivity. The ease of recovery using an external magnetic field, high activity, and the intrinsic stability of the catalyst make this protocol economic and sustainable.

摘要

一种磁性纳米颗粒负载的钯催化剂可由廉价的起始原料轻松制备，并已证明能以高周转数（TON）和优异的选择性催化各种氧化反应。利用外部磁场易于回收、高活性以及催化剂的固有稳定性使得该方法经济且可持续。

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