Maayan Galia, Ward Michael D, Kirshenbaum Kent
Department of Chemistry and the Molecular Design Institute, New York University, New York, New York 10003-6688, USA.
Chem Commun (Camb). 2009 Jan 7(1):56-8. doi: 10.1039/b810875g. Epub 2008 Nov 17.
N-substituted glycine peptoid oligomers bearing hydroxyquinoline ligands form complexes with Cu(ii) and Co(ii) in which the chiral helical secondary structure of the foldamers is enhanced upon metal binding and establishes a stereogenic environment for metal coordination.
带有羟基喹啉配体的N-取代甘氨酸类肽低聚物与Cu(ii)和Co(ii)形成配合物，其中折叠体的手性螺旋二级结构在金属结合时得到增强，并为金属配位建立了一个手性环境。
