S-自由基对分子氧的活化：炔烃氧化为α-二酮新反应的实验与计算研究
Activation of molecular oxygen by S-radicals: experimental and computational studies on a novel oxidation of alkynes to alpha-diketones.
作者信息
Tan Kristine J, Wille Uta
机构信息
ARC Centre of Excellence for Free Radical Chemistry and Biotechnology, School of Chemistry and BIO21 Institute, The University of Melbourne, Victoria, 3052, Australia.
出版信息
Chem Commun (Camb). 2008 Dec 14(46):6239-41. doi: 10.1039/b815358b. Epub 2008 Oct 16.
DOI:10.1039/b815358b
PMID:19082132
Abstract
Thiylperoxyl radicals are the suggested reactive key-intermediates in the oxidation of bis-aromatic alkynes to alpha-diketones using molecular oxygen "activated" by thiyl radicals.
摘要
硫自由基过氧自由基被认为是在硫自由基“活化”的分子氧将双芳基炔烃氧化为α-二酮的过程中的关键反应性中间体。
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