Saimandir Jayakrishnan, Gopal Madhuban, Walia Suresh
Division of Agricultural Chemicals, Indian Agricultural Research Institute, New Delhi 110012, India.
Pest Manag Sci. 2009 Feb;65(2):210-5. doi: 10.1002/ps.1670.
Thiacloprid [(Z)-3-(6-chloro-3-pyridylmethyl)-1,3-thiazolidin-2-ylidenecyanamide; Calypso] is a systemic insecticide having persistence in the plant system. It was chosen for the management of the eggplant shoot and fruit borer, Leucinodes orbonalis Guen. Management of this insect pest is difficult because it harbours inside the shoot and fruit portions of eggplant. The persistence of thiacloprid on eggplant has not been studied in India. The Food and Agriculture Organisation (FAO) has proposed its maximum residue limit (MRL) on eggplant as 0.7 mg kg(-1), and there is a need to validate this value. Since residues were found to be above this level, five different decontamination agents were tested for the decontamination of thiacloprid from eggplant.
The half-life of thiacloprid was 11.1 and 11.6 days from trials in 2 years. Safety factors such as theoretical maximum daily intake (TMDI) and maximum permissible intake (MPI) were used to arrive at a risk assessment to human health from the analytical data obtained from the field trials. Thiacloprid at the doses tested (30 and 60 g AI ha(-1)) was not effective in managing eggplant fruit borer. A waiting period of 3 days before harvest of the fruits after insecticide application and a processing factor (PF) could not ensure a sufficient margin of safety (MOS). Subjecting the data to a processing factor of 60% could not bring the residues below the proposed MRL.
Thiacloprid is not found to be an appropriate and effective agent for application to eggplant. Either the proposed MRL needs to be revised or good agricultural practice involving thiacloprid for plant protection in eggplant cultivation is required.
噻虫啉[(Z)-3-(6-氯-3-吡啶基甲基)-1,3-噻唑烷-2-亚基氰胺;Calypso]是一种在植物系统中具有持久性的内吸性杀虫剂。它被选用于防治茄子蛀茎虫和茄黄斑螟,茄黄斑螟学名Leucinodes orbonalis Guen。这种害虫的防治难度较大,因为它藏匿于茄子的茎部和果实内部。在印度,尚未对噻虫啉在茄子上的持久性进行研究。联合国粮食及农业组织(FAO)提议茄子中噻虫啉的最大残留限量(MRL)为0.7毫克/千克(-1),因此有必要对该数值进行验证。由于发现残留量高于此水平,对五种不同的去污剂进行了测试,以去除茄子上的噻虫啉。
在两年的试验中,噻虫啉的半衰期分别为11.1天和11.6天。利用理论最大日摄入量(TMDI)和最大允许摄入量(MPI)等安全系数,根据田间试验获得的分析数据对人类健康进行风险评估。所测试剂量(30和60克有效成分/公顷(-1))的噻虫啉对防治茄子蛀果螟无效。施药后收获果实前3天的等待期以及加工因子(PF)无法确保足够的安全边际(MOS)。将数据应用60%的加工因子并不能使残留量低于提议的MRL。
未发现噻虫啉是一种适用于茄子的有效药剂。要么需要修订提议的MRL,要么需要在茄子种植中采用涉及噻虫啉的良好农业规范进行植物保护。