Pesticide Residue Analysis Laboratory, Department of Entomology, Punjab Agricultural University, Ludhiana, 141004 Punjab, India.
Environ Monit Assess. 2013 Sep;185(9):7935-43. doi: 10.1007/s10661-013-3145-z. Epub 2013 Mar 3.
Thiacloprid, a neonicotinoid insecticide with novel mode of action, is found to be effective against several lepidopteran as well as hemipteran pests. The present studies were carried out to observe the persistence pattern of thiacloprid on brinjal and to suggest suitable waiting period for the safety of consumers. Persistence of thiacloprid in brinjal was studied following three applications of thiacloprid (Alanto 240 SC) at 180 and 360 g a.i. ha(-1) at 7 days interval. Residues of thiacloprid in brinjal were estimated by high-performance liquid chromatography and were confirmed by liquid chromatography-mass spectrometry. The average initial deposits of thiacloprid were observed to be 0.48 and 1.05 mg kg(-1) on the brinjal fruit following third application of thiacloprid at recommended and double the recommended dosages, respectively. Half-life periods for thiacloprid were found to be 0.47 and 0.50 days at single and double the application rates, respectively. Residues of thiacloprid declined below its limit of quantification of 0.05 mg kg(-1) after 3 and 5 days, respectively, at recommended and double the recommended application rates. Therefore, the use of thiacloprid does not seem to pose any risk hazard and a waiting period of 1 day is suggested for safe consumption of brinjal fruits.
噻虫啉是一种新型作用模式的新烟碱类杀虫剂,被发现对几种鳞翅目和半翅目害虫有效。本研究旨在观察噻虫啉在茄子上的残留模式,并为消费者的安全提出合适的等待期。在推荐剂量和推荐剂量的两倍的间隔 7 天,分别用噻虫啉(Alanto 240 SC)三次处理茄子,研究了噻虫啉在茄子上的残留情况。采用高效液相色谱法测定噻虫啉在茄子中的残留量,并通过液相色谱-质谱法进行验证。第三次施药后,噻虫啉在茄子果实上的初始平均沉积量分别为 0.48 和 1.05mg/kg,推荐剂量和推荐剂量的两倍。噻虫啉的半衰期在单次和双次施药率下分别为 0.47 和 0.50 天。在推荐剂量和推荐剂量的两倍下,噻虫啉的残留量分别在 3 天和 5 天后低于其限量 0.05mg/kg。因此,使用噻虫啉似乎不会带来任何风险,建议在安全食用茄子之前等待 1 天。