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外延石墨烯的化学修饰:芳基的自发接枝

Chemical modification of epitaxial graphene: spontaneous grafting of aryl groups.

作者信息

Bekyarova Elena, Itkis Mikhail E, Ramesh Palanisamy, Berger Claire, Sprinkle Michael, de Heer Walt A, Haddon Robert C

机构信息

Center for Nanoscale Science and Engineering, Department of Chemistry, University of California, Riverside, California 92521, USA.

出版信息

J Am Chem Soc. 2009 Feb 4;131(4):1336-7. doi: 10.1021/ja8057327.

Abstract

The addition of nitrophenyl groups to the surface of few-layer epitaxial graphene (EG) by the formation of covalent carbon-carbon bonds changed the electronic structure and transport properties of the EG from near-metallic to semiconducting.

摘要

通过形成共价碳-碳键在少层外延石墨烯(EG)表面添加硝基苯基,改变了EG的电子结构和输运性质,使其从近金属性转变为半导体性。

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