Inglis Andrew J, Sinnwell Sebastian, Stenzel Martina H, Barner-Kowollik Christopher
Preparative Macromolecular Chemistry, Institut für Technische Chemie und Polymerchemie, Universität Karlsruhe (TH)/Karlsruhe Institute of Technology, Engesserstrasse 18, 76128 Karlsruhe, Germany.
Angew Chem Int Ed Engl. 2009;48(13):2411-4. doi: 10.1002/anie.200805993.
Block copolymers in seconds: Catalyst-free, ambient-temperature click conjugation of individual polymer strands becomes possible using novel ATRP-derived cyclopentadienyl-capped polymers in an extremely rapid hetero-Diels-Alder cycloaddition with macromolecules equipped with electron-deficient dithioester end groups prepared by the RAFT process.
使用新型原子转移自由基聚合（ATRP）衍生的环戊二烯基封端聚合物，在与通过可逆加成-断裂链转移（RAFT）过程制备的带有缺电子二硫酯端基的大分子进行极快速的杂Diels-Alder环加成反应中，实现了无催化剂、室温下单个聚合物链的点击共轭。
