醇与炔烃的自由基引发偶联反应：形成的是C-C键而非C-O键。
Free-radical-initiated coupling reaction of alcohols and alkynes: not C-O but C-C bond formation.
作者信息
Liu Zhong-Quan, Sun Liang, Wang Jian-Guo, Han Jie, Zhao Yan-Kai, Zhou Bo
机构信息
State Key Laboratory of Applied Organic Chemistry and Department of Chemistry, Lanzhou University, Lanzhou 730000, PR China.
出版信息
Org Lett. 2009 Mar 19;11(6):1437-9. doi: 10.1021/ol900145u.
PMID:19243113
Abstract
This work demonstrates an efficient method to prepare allylic alcohols via direct C-C bond formation using electron-rich alkynes and aliphatic alcohols initiated by tert-butyl hydroperoxide.
摘要
这项工作展示了一种高效的方法，该方法通过使用富电子炔烃和由叔丁基过氧化氢引发的脂肪醇，经由直接形成碳-碳键来制备烯丙醇。
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