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通过聚阴离子形成和芘激基缔合物发射进行葡萄糖传感。

Glucose sensing via polyanion formation and induced pyrene excimer emission.

作者信息

Yu Cong, Yam Vivian Wing-Wah

机构信息

Center for Carbon-Rich Molecular and Nanoscale Metal-Based Materials Research, Department of Chemistry and HKU-CAS Joint Laboratory on New Materials, The University of Hong Kong, Pokfulam Road, Hong Kong, PR China.

出版信息

Chem Commun (Camb). 2009 Mar 21(11):1347-9. doi: 10.1039/b820397k. Epub 2009 Feb 10.

Abstract

Glucose binding to boronic acid functional groups attached to a synthetic polymer in an aqueous solution effectively turns the polymer into a polyanion, which induces the aggregation of the positively charged trimethylpentylammonium pyrene derivative, leading to a strong excimer emission and the development of a ratiometric fluorescence glucose probe.

摘要

在水溶液中,葡萄糖与连接在合成聚合物上的硼酸官能团结合,有效地将聚合物转变为聚阴离子,这会诱导带正电荷的三甲基戊基铵芘衍生物发生聚集,从而产生强烈的准分子发射,并开发出一种比率荧光葡萄糖探针。

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