Department of Chemistry, College of Chemistry and Chemical Engineering, and MOE Key Laboratory of Analytical Sciences, Xiamen University, Xiamen 361005, China.
J Am Chem Soc. 2013 Feb 6;135(5):1700-3. doi: 10.1021/ja311442x. Epub 2013 Jan 29.
Aggregates of an amphiphilic monoboronic acid bearing a hydrophobic pyrene fluorophore were employed for highly modulating, sensitive, and selective ratiometric fluorescent sensing of glucose in aqueous solution. The selectivity for glucose was improved by "knock-out" binding of fructose by phenylboronic acid.
具有疏水性芘荧光团的两亲性单硼酸的聚集体被用于高度调节、灵敏和选择性的比色荧光传感水溶液中的葡萄糖。通过苯硼酸的“敲除”结合作用提高了对葡萄糖的选择性。