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通过聚集进行葡萄糖感应,并利用“敲除”结合来提高选择性。

Glucose sensing via aggregation and the use of "knock-out" binding to improve selectivity.

机构信息

Department of Chemistry, College of Chemistry and Chemical Engineering, and MOE Key Laboratory of Analytical Sciences, Xiamen University, Xiamen 361005, China.

出版信息

J Am Chem Soc. 2013 Feb 6;135(5):1700-3. doi: 10.1021/ja311442x. Epub 2013 Jan 29.

DOI:10.1021/ja311442x
PMID:23317305
Abstract

Aggregates of an amphiphilic monoboronic acid bearing a hydrophobic pyrene fluorophore were employed for highly modulating, sensitive, and selective ratiometric fluorescent sensing of glucose in aqueous solution. The selectivity for glucose was improved by "knock-out" binding of fructose by phenylboronic acid.

摘要

具有疏水性芘荧光团的两亲性单硼酸的聚集体被用于高度调节、灵敏和选择性的比色荧光传感水溶液中的葡萄糖。通过苯硼酸的“敲除”结合作用提高了对葡萄糖的选择性。

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