氧鎓盐/亚氯酸钠：一种便捷的催化体系，可将伯醇一锅氧化为羧酸，底物适用性广泛。
Oxoammonium salt/NaClO2: an expedient, catalytic system for one-pot oxidation of primary alcohols to carboxylic acids with broad substrate applicability.
作者信息
Shibuya Masatoshi, Sato Takahisa, Tomizawa Masaki, Iwabuchi Yoshiharu
机构信息
Department of Organic Chemistry, Graduate School of Pharmaceutical Sciences, Tohoku University, 6-3 Aobayama, Sendai, 980-8578, Japan.
出版信息
Chem Commun (Camb). 2009 Apr 7(13):1739-41. doi: 10.1039/b822944a. Epub 2009 Feb 11.
DOI:10.1039/b822944a
PMID:19294280
Abstract
A facile, green, one-pot oxidation of primary alcohols to carboxylic acids with broad substrate applicability has been developed by employing an expedient catalytic system consisting of 1-Me-AZADO+X-/NaClO2.
摘要
通过使用由1-Me-AZADO+X-/NaClO₂组成的便捷催化体系，已开发出一种简便、绿色的一锅法将伯醇氧化为羧酸的方法，该方法具有广泛的底物适用性。
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