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深共熔溶剂的多功能结构导向作用及其在生成用于气体储存的孔隙率和开放金属位点方面的意义。

Versatile structure-directing roles of deep-eutectic solvents and their implication in the generation of porosity and open metal sites for gas storage.

作者信息

Zhang Jian, Wu Tao, Chen Shumei, Feng Pingyun, Bu Xianhui

机构信息

Department of Chemistry and Biochemistry, California State University, Long Beach, 1250 Bellflower Boulevard, Long Beach, CA 90840, USA.

出版信息

Angew Chem Int Ed Engl. 2009;48(19):3486-90. doi: 10.1002/anie.200900134.

DOI:10.1002/anie.200900134
PMID:19343752
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2790049/
Abstract

Trap it in and burn it out: A deep-eutectic solvent provides a versatile medium for the creation of highly stable porous frameworks encapsulating neutral coordinating ligand molecules, which can escape intact from the pores upon heating to form crystals directly, leaving behind permanent porosity and coordinatively unsaturated metal sites with potential applications in gas storage and catalysis.

摘要

将其捕获并烧掉

一种深共熔溶剂为创建高度稳定的多孔框架提供了一种通用介质，该框架封装中性配位配体分子，加热时这些分子可完整地从孔中逸出直接形成晶体，留下永久孔隙率和配位不饱和金属位点，在气体存储和催化方面具有潜在应用。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/649e/2790049/caa47e9c4420/nihms147049f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/649e/2790049/7c0b1580e271/nihms147049f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/649e/2790049/108dcdc07d2e/nihms147049f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/649e/2790049/6fd8d085355a/nihms147049f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/649e/2790049/cb557fd4e9ba/nihms147049f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/649e/2790049/caa47e9c4420/nihms147049f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/649e/2790049/7c0b1580e271/nihms147049f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/649e/2790049/108dcdc07d2e/nihms147049f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/649e/2790049/6fd8d085355a/nihms147049f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/649e/2790049/cb557fd4e9ba/nihms147049f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/649e/2790049/caa47e9c4420/nihms147049f5.jpg

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