官能团相容性。在乙烯基碘存在下还原炔丙醇。
Functional group compatibility. Propargyl alcohol reduction in the presence of a vinyl iodide.
作者信息
Denton Richard W, Parker Kathlyn A
机构信息
Department of Chemistry, SUNY Stony Brook, Stony Brook, New York 11794-3400, USA.
出版信息
Org Lett. 2009 Jul 2;11(13):2722-3. doi: 10.1021/ol900927a.
Abstract
Vinyl iodides are stable to the reduction of propargyl alcohols to cis allylic alcohols by hydrogen over Pd/CaCO(3) in hexane. They are also stable to the reduction of propargyl alcohols to saturated alcohols by hydrogen over Crabtree's iridium catalyst in CH(2)Cl(2).
摘要
在己烷中，通过氢气在钯/碳酸钙上的作用，将炔丙醇还原为顺式烯丙醇时，碘代乙烯是稳定的。在二氯甲烷中，通过氢气在克拉布特里铱催化剂上的作用，将炔丙醇还原为饱和醇时，碘代乙烯也是稳定的。
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