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微波辅助离子液体合成。

Microwave-assisted synthesis using ionic liquids.

机构信息

Programa de Ingeniería Molecular, Instituto Mexicano del Petróleo, Eje Central L. Cárdenas 152, 07730, Mexico, DF, Mexico.

出版信息

Mol Divers. 2010 Feb;14(1):3-25. doi: 10.1007/s11030-009-9159-3. Epub 2009 Jun 9.

Abstract

The research and application of green chemistry principles have led to the development of cleaner processes. In this sense, during the present century an ever-growing number of studies have been published describing the use of ionic liquids (ILs) as solvents, catalysts, or templates to develop more environmentally friendly and efficient chemical transformations for their use in both academia and industry. The conjugation of ILs and microwave irradiation as a non-conventional heating source has shown evident advantages when compared to conventional synthetic procedures for the generation of fast, efficient, and environmental friendly synthetic methodologies. This review focuses on the advances in the use of ILs in organic, polymers and materials syntheses under MW irradiation conditions.

摘要

绿色化学原则的研究和应用催生了更清洁的工艺。从这个意义上说,本世纪以来,越来越多的研究描述了离子液体(ILs)作为溶剂、催化剂或模板的使用,以开发更环保、更高效的化学转化,用于学术界和工业界。与传统的合成方法相比,ILs 与微波辐射的结合作为一种非传统的加热源,在生成快速、高效和环保的合成方法方面显示出明显的优势。本文综述了微波辐射条件下 ILs 在有机、聚合物和材料合成中的应用进展。

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