Department of Chemistry, La Trobe University, Victoria 3086, Australia.
Analyst. 2009 Jul;134(7):1297-8. doi: 10.1039/b905024h. Epub 2009 Apr 21.
Chemical reactions between certain bis-cyclometalated iridium complexes, cerium(IV) and organic reducing agents in aqueous solution produce an emission of light which in some cases is more intense than that from analogous reactions with conventional ruthenium-based reagents, thus providing a new avenue for chemically-initiated luminescence detection.
某些双环金属铱配合物、四价铈与水相中的有机还原剂之间的化学反应会产生光的发射,在某些情况下,其强度比使用传统基于钌的试剂进行类似反应时要强,从而为化学引发的发光检测提供了新途径。