Kochetkov N K, Klimov E M, Malysheva N N, Demchenko A V
N.D. Zelinsky Institute of Organic Chemistry, Academy of Sciences of the U.S.S.R., Moscow.
Carbohydr Res. 1991 Jun 10;212:77-91. doi: 10.1016/0008-6215(91)84047-i.
A new stereospecific method for 1,2-cis-glycosylation involves the reaction of 1,2-trans-glycosyl thiocyanates with sugar trityl ethers in the presence of triphenylmethylium perchlorate. The method has been applied to give disaccharide derivatives with (1----6), (1----3), and (1----2) linkages.
一种新的用于1,2-顺式糖基化的立体专一性方法，涉及1,2-反式糖基硫氰酸酯与糖三苯甲基醚在高氯酸三苯甲基鎓存在下的反应。该方法已被用于制备具有(1→6)、(1→3)和(1→2)连接的二糖衍生物。
