以α'-羟基烯酮作为酰化试剂的催化酰胺形成反应。
Catalytic amide formation with alpha'-hydroxyenones as acylating reagents.
作者信息
Chiang Pei-Chen, Kim Yoonjoo, Bode Jeffrey W
机构信息
Roy and Diana Vagelos Laboratories, Department of Chemistry, University of Pennsylvania, Philadelphia, USA.
出版信息
Chem Commun (Camb). 2009 Aug 14(30):4566-8. doi: 10.1039/b909360e. Epub 2009 Jul 6.
Abstract
Alpha'-hydroxyenones undergo clean, catalytic amidations with amines promoted by the combination of an N-heterocyclic carbene and 1,2,4-triazole.
摘要
α'-羟基烯酮在氮杂环卡宾和1,2,4-三唑的组合促进下，能与胺进行清洁的催化酰胺化反应。
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