Gallego Eva, Roca Xavier, Perales Jose Francisco, Guardino Xavier
Environmental Centre Laboratory, Polytechnic University of Catalonia (LCMA-UPC), Avda, Diagonal 647, E 08028 Barcelona, Spain.
J Environ Sci (China). 2009;21(3):333-9. doi: 10.1016/s1001-0742(08)62273-1.
A methodology for identifying volatile organic compounds (VOCs) and determining air quality of indoor air has been developed. The air samples are collected using pump samplers by the inhabitants when they perceive odorous and/or discomfort episodes. Glass multi-sorbent tubes are connected to the pump samplers for the retention of VOC. The analysis is performed by automatic thermal desorption (ATD) coupled with gas chromatography-mass spectrometry (GC/MS). This methodology can be applied in cases of sick building syndrome (SBS) evaluation, in which building occupants experience a series of varied symptoms that appear to be linked to time spent in the building. Chemical pollutants concentrations (e.g., VOC) have been described to contribute to SBS. To exemplify the methodology, a qualitative determination and an evaluation of existing VOC were performed in a dwelling where the occupants experienced the SBS symptoms. Higher total VOC (TVOC) levels were detected during episodes in indoor air (1.33 +/- 1.53 mg/m3) compared to outdoor air (0.71 +/- 0.46 mg/m3). The concentrations of individual VOCs, such as ethanol, acetone, isopropanol, 1-butanol, acetic acid, acetonitrile and 1-methoxy-2-propanol, were also higher than the expected for a standard dwelling. The external source of VOC was found to be an undeclared activity of storage and manipulation of solvents located at the bottom of a contiguous building.
已开发出一种用于识别挥发性有机化合物(VOCs)和测定室内空气质量的方法。当居民察觉到有异味和/或不适情况时,使用泵式采样器采集空气样本。玻璃多吸附剂管连接到泵式采样器以保留VOC。分析通过自动热解吸(ATD)与气相色谱 - 质谱联用(GC/MS)进行。该方法可应用于病态建筑综合症(SBS)评估案例,在这类案例中,建筑居住者会经历一系列似乎与在建筑物内停留时间有关的各种症状。化学污染物浓度(如VOC)已被描述为导致SBS的因素。为举例说明该方法,在一个居住者出现SBS症状的住宅中对现有VOC进行了定性测定和评估。与室外空气(0.71±0.46毫克/立方米)相比,室内空气中异味发作期间检测到的总挥发性有机化合物(TVOC)水平更高(1.33±1.53毫克/立方米)。乙醇、丙酮、异丙醇、1 - 丁醇、乙酸、乙腈和1 - 甲氧基 - 2 - 丙醇等单个VOC的浓度也高于标准住宅的预期值。发现VOC的外部来源是相邻建筑物底部未申报的溶剂储存和处理活动。