Chen Xiufang, Zhang Jinshui, Fu Xianzhi, Antonietti Markus, Wang Xinchen
Research Institute of Photocatalysis, State Key Laboratory Breeding Base of Photocatalysis, Fuzhou University, Fuzhou, 350002, PR China.
J Am Chem Soc. 2009 Aug 26;131(33):11658-9. doi: 10.1021/ja903923s.
A bioinspired iron-based catalyst with semiconductor photocatalytic functions in combination with a high surface area holds promise for synthetic chemistry via combining photocatalysis with organosynthesis. Here exemplified for phenol synthesis, Fe-g-C(3)N(4)/SBA-15 is able to oxidize benzene to phenol with H(2)O(2) even without the aid of strong acids or alkaline promoters. By taking advantage of both catalysis and photocatalysis functions of g-C(3)N(4) nanoparticles, the yield of the phenol can be markedly promoted.
一种具有半导体光催化功能且比表面积高的仿生铁基催化剂，通过将光催化与有机合成相结合，在合成化学领域具有广阔前景。以苯酚合成为例，Fe-g-C(3)N(4)/SBA-15即使在不借助强酸或碱性促进剂的情况下，也能够利用H(2)O(2)将苯氧化为苯酚。通过利用g-C(3)N(4)纳米颗粒的催化和光催化功能，可以显著提高苯酚的产率。
