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基于催化纳米马达的化学传感:基于运动的痕量银检测

Chemical sensing based on catalytic nanomotors: motion-based detection of trace silver.

作者信息

Kagan Daniel, Calvo-Marzal Percy, Balasubramanian Shankar, Sattayasamitsathit Sirilak, Manesh Kalayil Manian, Flechsig Gerd-Uwe, Wang Joseph

机构信息

Department of Nanoengineering, University of California San Diego, La Jolla, California 92093, USA.

出版信息

J Am Chem Soc. 2009 Sep 2;131(34):12082-3. doi: 10.1021/ja905142q.

DOI:10.1021/ja905142q
PMID:19670862
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2734325/
Abstract

A motion-based chemical sensing involving fuel-driven nanomotors is demonstrated. The new protocol relies on the use of an optical microscope for tracking changes in the speed of nanowire motors in the presence of the target analyte. Selective and sensitive measurements of trace silver ions are illustrated based on the dramatic and specific acceleration of bimetal nanowire motors in the presence of silver. Such nanomotor-based measurements would lead to a wide range of novel and powerful chemical and biological sensing protocols.

摘要

展示了一种基于运动的化学传感,该传感涉及燃料驱动的纳米马达。新方案依赖于使用光学显微镜来跟踪在存在目标分析物的情况下纳米线马达速度的变化。基于双金属纳米线马达在银存在下显著且特定的加速,说明了对痕量银离子的选择性和灵敏测量。这种基于纳米马达的测量将导致一系列新颖且强大的化学和生物传感方案。

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本文引用的文献

1
Electrochemically-triggered motion of catalytic nanomotors.催化纳米马达的电化学触发运动。
Chem Commun (Camb). 2009 Aug 14(30):4509-11. doi: 10.1039/b909227g. Epub 2009 Jun 24.
2
Schooling behavior of light-powered autonomous micromotors in water.水中光驱动自主微电机的游动行为
Angew Chem Int Ed Engl. 2009;48(18):3308-12. doi: 10.1002/anie.200804704.
3
Characterization of silver ions adsorbed on gold nanorods: surface analysis by using surface-assisted laser desorption/ionization time-of-flight mass spectrometry.吸附在金纳米棒上的银离子的表征:使用表面辅助激光解吸/电离飞行时间质谱进行表面分析。
Chem Commun (Camb). 2009 Apr 7(13):1754-6. doi: 10.1039/b821402f. Epub 2009 Feb 13.
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Label-free DNA sensor based on surface charge modulated ionic conductance.基于表面电荷调制离子电导的无标记DNA传感器。
ACS Nano. 2009 Apr 28;3(4):1004-10. doi: 10.1021/nn900113x.
5
Ultrafast catalytic alloy nanomotors.超快催化合金纳米马达
Angew Chem Int Ed Engl. 2008;47(48):9349-51. doi: 10.1002/anie.200803841.
6
Synthetic nanomotors in microchannel networks: directional microchip motion and controlled manipulation of cargo.微通道网络中的合成纳米马达:定向微芯片运动及货物的受控操纵
J Am Chem Soc. 2008 Jul 2;130(26):8164-5. doi: 10.1021/ja803529u. Epub 2008 Jun 6.
7
Self-motile colloidal particles: from directed propulsion to random walk.自驱动胶体粒子:从定向推进到随机游走
Phys Rev Lett. 2007 Jul 27;99(4):048102. doi: 10.1103/PhysRevLett.99.048102.
8
Bipolar electrochemical mechanism for the propulsion of catalytic nanomotors in hydrogen peroxide solutions.过氧化氢溶液中催化纳米马达推进的双极电化学机制。
Langmuir. 2006 Dec 5;22(25):10451-6. doi: 10.1021/la0615950.
9
Catalytically induced electrokinetics for motors and micropumps.用于电机和微型泵的催化诱导动电现象
J Am Chem Soc. 2006 Nov 22;128(46):14881-8. doi: 10.1021/ja0643164.
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Quantitation of metal content in the silver-assisted growth of gold nanorods.银辅助生长金纳米棒过程中金属含量的定量分析。
J Phys Chem B. 2006 Mar 9;110(9):3990-4. doi: 10.1021/jp0570972.