Mak Yim Ling, Taniyasu Sachi, Yeung Leo W Y, Lu Guohui, Jin Ling, Yang Yongliang, Lam Paul K S, Kannan Kurunthachalam, Yamashita Nobuyoshi
Centre for Coastal Pollution and Conservation, Department of Biology and Chemistry, City University of Hong Kong, Tat Chee Avenue, Kowloon, Hong Kong SAR, People's Republic of China.
Environ Sci Technol. 2009 Jul 1;43(13):4824-9. doi: 10.1021/es900637a.
The recent development of a sensitive and accurate analytical method for the analysis of 20 perfluorinated compounds (PFCs), including several short-chain PFCs, has enabled their quantification in tap water collected in China, Japan, India, the United States, and Canada between 2006 and 2008. Of the PFCs measured, PFOS, PFHxS, PFBS, PFPrS, PFEtS, PFOSA, N-EtFOSAA, PFDoDA, PFUnDA, PFDA, PFNA, PFHpA, PFHxA, PFPeA, PFBA, and PFPrA were found at detectable concentrations in the tap water samples. The water samples from Shanghai (China) contained the greatest concentrations of total PFCs (arithmetic mean = 130 ng/L), whereas those from Toyama (Japan) contained only 0.62 ng/L. In addition to PFOS and PFOA, short-chain PFCs such as PFHxS, PFBS, PFHxA, and PFBA were found to be prevalent in drinking water. According to the health-based values (HBVs) and advisory guidelines derived for PFOS, PFOA, PFBA, PFHxS, PFBS, PFHxA, and PFPeA by the U.S.EPA and the Minnesota Department of Health, tap water may not pose an immediate health risk to consumers.
最近开发出一种灵敏且准确的分析方法,可用于分析20种全氟化合物(PFCs),包括几种短链全氟化合物,这使得能够对2006年至2008年间在中国、日本、印度、美国和加拿大采集的自来水样本中的这些化合物进行定量分析。在所检测的全氟化合物中,全氟辛烷磺酸(PFOS)、全氟己烷磺酸(PFHxS)、全氟丁烷磺酸(PFBS)、全氟丙磺酸(PFPrS)、全氟乙磺酸(PFEtS)、全氟辛烷磺酸酐(PFOSA)、N-乙基全氟辛烷磺酸酰胺(N-EtFOSAA)、全氟癸二酸(PFDoDA)、全氟十一烷酸(PFUnDA)、全氟癸酸(PFDA)、全氟萘酸(PFNA)、全氟庚酸(PFHpA)、全氟己酸(PFHxA)、全氟戊酸(PFPeA)、全氟丁酸(PFBA)和全氟丙酸(PFPrA)在自来水样本中均检测到了可检出浓度。来自上海(中国)的水样中全氟化合物的总浓度最高(算术平均值 = 130 ng/L),而来自富山(日本)的水样中仅含有0.62 ng/L。除了全氟辛烷磺酸和全氟辛酸外,短链全氟化合物如全氟己烷磺酸、全氟丁烷磺酸、全氟己酸和全氟丁酸在饮用水中也很普遍。根据美国环境保护局(U.S.EPA)和明尼苏达州卫生部针对全氟辛烷磺酸、全氟辛酸、全氟丁酸、全氟己烷磺酸、全氟丁烷磺酸、全氟己酸和全氟戊酸制定的基于健康的值(HBVs)和咨询指南,自来水可能不会对消费者造成直接健康风险。