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结合过渡金属催化和有机催化:催化的一个广泛新概念。

Combining transition metal catalysis and organocatalysis: a broad new concept for catalysis.

机构信息

Key Laboratory of Medicinal Chemistry for Natural Resource, Ministry of Education, School of Chemical Science and Technology, Yunnan University, Kunming, Yunnan 650091, China.

出版信息

Chem Soc Rev. 2009 Sep;38(9):2745-55. doi: 10.1039/b901258n. Epub 2009 Jun 2.

DOI:10.1039/b901258n
PMID:19690751
Abstract

In recent years, the concept of combining transition metal catalysis and organocatalysis has emerged as a promising strategy for developing new and valuable reactions, and has attracted considerable attention as it could potentially enable unprecedented transformations not currently possible by use of the transition metal complex or the organocatalyst alone. In this critical review, this strategy is illustrated with several recent outstanding examples, with the aim of shedding light on the synthetic utilities and potentials of this concept as a novel tool in organic synthesis (118 references).

摘要

近年来,将过渡金属催化和有机催化相结合的概念已经成为开发新的有价值的反应的一种很有前途的策略,并且由于它有可能使目前仅使用过渡金属配合物或有机催化剂不可能实现的转化成为可能,因此引起了相当大的关注。在这篇评论中,用几个最近的杰出例子来说明了这一策略,旨在阐明这一概念作为有机合成中的一种新工具的合成实用性和潜力(118 个参考文献)。

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