催化对映选择性分子内氧化还原反应：环合的四氢喹啉。
Catalytic enantioselective intramolecular redox reactions: ring-fused tetrahydroquinolines.
机构信息
Department of Chemistry and Chemical Biology, Rutgers, The State University of New Jersey,Piscataway, New Jersey 08854, USA.
出版信息
J Am Chem Soc. 2009 Sep 23;131(37):13226-7. doi: 10.1021/ja905213f.
PMID:19711900
Abstract
The first example of a catalytic enantioselective intramolecular hydride shift/ring closure reaction is reported. This redox neutral reaction cascade allows for the efficient formation of ring-fused tetrahydroquinolines in high enantioselectivities.
摘要
首例催化对映选择性分子内氢化物转移/环化反应的实例被报道。这种氧化还原中性反应级联反应能够以高对映选择性有效地形成环合的四氢喹啉。
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