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Simple chiral chain dienes as ligands for Rh(I)-catalyzed conjugated additions.

作者信息

Hu Xichao, Zhuang Minyang, Cao Ziping, Du Haifeng

机构信息

Beijing National Laboratory of Molecular Sciences, CAS Key Laboratory of Molecular Recognition and Function, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China.

出版信息

Org Lett. 2009 Oct 15;11(20):4744-7. doi: 10.1021/ol901949n.

DOI:10.1021/ol901949n
PMID:19761192
Abstract

This paper describes that a simple and readily available chain diene (3R,4R)-hexa-1,5-diene-3,4-diol (L1) was successfully utilized as a novel steering ligand for Rh(I)-catalyzed asymmetric conjugated additions. Encouraging yields and ee's have been achieved, which may provide a new and practical direction for designing chiral diene ligands in the future.

摘要

相似文献

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Simple chiral chain dienes as ligands for Rh(I)-catalyzed conjugated additions.
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2
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Tandem Aldol Condensation - Platinacycle-Catalyzed Addition Reactions of Aldehydes, Methyl Ketones and Arylboronic Acids.
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