Beijing National Laboratory of Molecular Sciences, CAS Key Laboratory of Molecular Recognition and Function, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China.
Org Lett. 2010 Dec 3;12(23):5482-5. doi: 10.1021/ol1023536. Epub 2010 Nov 1.
A variety of readily accessible vicinal-diamine-based chiral chain dienes were successfully synthesized and utilized as steering ligands for rhodium-catalyzed conjugated additions of organoboronic acids to α,β-unsaturated carbonyl compounds to afford the desired adducts in good to excellent yields and ee's.
成功合成了多种易得的邻二胺基手性链二烯，并将其用作铑催化的有机硼酸与α,β-不饱和羰基化合物的共轭加成反应的手性导向配体，以高至优异的收率和对映选择性得到所需产物。
